Titanium(III) phosphide

Titanium(III) phosphide
Names
	Other names titanium monophosphide
Identifiers
CAS Number	12037-65-9 ;
3D model (JSmol)	Interactive image;
ChemSpider	74768;
ECHA InfoCard	100.031.680
EC Number	234-862-6;
PubChem CID	82856;
CompTox Dashboard (EPA)	DTXSID801014254 ;
	InChI InChI=1S/P.Ti Key: ADDWXBZCQABCGO-UHFFFAOYSA-N;
	SMILES P#[Ti];
Properties
Chemical formula	TiP
Molar mass	78.841 g/mol
Appearance	gray crystals
Density	4.08 g/cm3, solid
Melting point	>1400°C
Structure
Crystal structure	hexagonal
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Titanium(III) phosphide (TiP) is an inorganic chemical compound of titanium and phosphorus. Normally encountered as a grey powder,^[1] it is a metallic conductor with a high melting point.^[2] It is not attacked by common acids or water.^[1] Its physical properties stand in contrast to the group 1 and group 2 phosphides that contain the P³⁻ anion (such as Na₃P), which are not metallic and are readily hydrolysed.^[2] Titanium phosphide is classified as a "metal-rich phosphide", where extra valence electrons from the metal are delocalised.^[2]

Titanium phosphide can be prepared by the reaction of TiCl₄ and PH₃.^[1]

There are other titanium phosphide phases, including Ti₃P,^[3] Ti₂P,^[4] Ti₇P₄,^[5] Ti₅P₃,^[6] and Ti₄P₃.^[7]

Titanium phosphide should not be confused with titanium phosphate or titanium isopropoxide, both of which are sometimes known by the acronym TIP.

References

^ ^a ^b ^c ^d ^e D. L. Perry, S. L. Phillips (1995) Handbook of inorganic compounds CRC Press ISBN 0-8493-8671-3
^ ^a ^b ^c H.G. Von Schnering, W. Hönle. "Phosphides - Solid state chemistry" Encyclopedia of Inorganic Chemistry Ed. R. Bruce King (1994) John Wiley & Sons ISBN 0-471-93620-0
^ Halter, Ursula; Mrowietv, Michael; Weiss, Alarich (1986). "Hydrogen absorption in ϵ-Ti₃P". Journal of the Less Common Metals. 118 (2): 343–348. doi:10.1016/0022-5088(86)90185-2.
^ Gemmi, M.; Zou, X. D.; Hovmöller, S.; Migliori, A.; Vennström, M.; Andersson, Y. (2003). "Structure of Ti₂P solved by three-dimensional electron diffraction data collected with the precession technique and high-resolution electron microscopy". Acta Crystallogr. A59 (2): 117–126. Bibcode:2003AcCrA..59..117G. doi:10.1107/S0108767302022559. PMID 12604849.
^ Carrillo, C W.; Lundström, T (1979). "New Phases in the Ti-P and Ti-Cu-P Systems". Acta Chemica Scandinavica A. 33: 401–402. doi:10.3891/acta.chem.scand.33a-0401.
^ Carrillo-Cabrera, Wilder; Lundström, Torsten; Näsäkkälä, Elina; Caspersen, Leif Dyhrberg; Woldbæk, T.; Strand, T. G.; Sukhoverkhov, V. F. (1980). "Crystal Structure Refinement of α-Ti₅P₃". Acta Chemica Scandinavica A. 34: 415–419. doi:10.3891/acta.chem.scand.34a-0415.
^ Snell, Per-Olof; Lumme, Paavo; Karvonen, Pertti; Virtanen, Artturi I.; Paasivirta, Jaakko (1968). "Phase Relationships in the Ti-P System with some Notes on the Crystal Structures of TiP₂ and ZrP₂". Acta Chemica Scandinavica. 22: 1942–1952. doi:10.3891/acta.chem.scand.22-1942.

[Perry-1] D. L. Perry, S. L. Phillips (1995) Handbook of inorganic compounds CRC Press ISBN 0-8493-8671-3

[Schnering-2] H.G. Von Schnering, W. Hönle. "Phosphides - Solid state chemistry" Encyclopedia of Inorganic Chemistry Ed. R. Bruce King (1994) John Wiley & Sons ISBN 0-471-93620-0

[3] Halter, Ursula; Mrowietv, Michael; Weiss, Alarich (1986). "Hydrogen absorption in ϵ-Ti₃P". Journal of the Less Common Metals. 118 (2): 343–348. doi:10.1016/0022-5088(86)90185-2.

[4] Gemmi, M.; Zou, X. D.; Hovmöller, S.; Migliori, A.; Vennström, M.; Andersson, Y. (2003). "Structure of Ti₂P solved by three-dimensional electron diffraction data collected with the precession technique and high-resolution electron microscopy". Acta Crystallogr. A59 (2): 117–126. Bibcode:2003AcCrA..59..117G. doi:10.1107/S0108767302022559. PMID 12604849.

[5] Carrillo, C W.; Lundström, T (1979). "New Phases in the Ti-P and Ti-Cu-P Systems". Acta Chemica Scandinavica A. 33: 401–402. doi:10.3891/acta.chem.scand.33a-0401.

[6] Carrillo-Cabrera, Wilder; Lundström, Torsten; Näsäkkälä, Elina; Caspersen, Leif Dyhrberg; Woldbæk, T.; Strand, T. G.; Sukhoverkhov, V. F. (1980). "Crystal Structure Refinement of α-Ti₅P₃". Acta Chemica Scandinavica A. 34: 415–419. doi:10.3891/acta.chem.scand.34a-0415.

[7] Snell, Per-Olof; Lumme, Paavo; Karvonen, Pertti; Virtanen, Artturi I.; Paasivirta, Jaakko (1968). "Phase Relationships in the Ti-P System with some Notes on the Crystal Structures of TiP₂ and ZrP₂". Acta Chemica Scandinavica. 22: 1942–1952. doi:10.3891/acta.chem.scand.22-1942.

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